Volume 44, Issue 24 p. 12,457-12,464
Research Letter
Free Access

Attributable Human-Induced Changes in the Likelihood and Magnitude of the Observed Extreme Precipitation during Hurricane Harvey

Mark D. Risser,

Corresponding Author

Climate and Ecosystem Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA

Correspondence to: M. D. Risser,

mdrisser@lbl.gov

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Michael F. Wehner,

Computational Research Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA

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First published: 12 December 2017
Citations: 132

Abstract

Record rainfall amounts were recorded during Hurricane Harvey in the Houston, Texas, area, leading to widespread flooding. We analyze observed precipitation from the Global Historical Climatology Network with a covariate-based extreme value statistical analysis, accounting for both the external influence of global warming and the internal influence of El Niño–Southern Oscillation. We find that human-induced climate change likely increased the chances of the observed precipitation accumulations during Hurricane Harvey in the most affected areas of Houston by a factor of at least 3.5. Further, precipitation accumulations in these areas were likely increased by at least 18.8% (best estimate of 37.7%), which is larger than the 6–7% associated with an attributable warming of 1°C in the Gulf of Mexico and Clausius-Clapeyron scaling. In a Granger causality sense, these statements provide lower bounds on the impact of climate change and motivate further attribution studies using dynamical climate models.

1 Introduction

Hurricane Harvey made landfall on the coast of Texas on 26 August 2017 as a category 4 storm. Rather than proceeding to track inland and dissipate, Harvey stalled with a portion of the storm system remaining over the warm waters of the Gulf of Mexico for another 4 days. While damages from high winds were significant, it was the unprecedented amount of rain that fell on the greater Houston area from 25 to 31 August and the resultant inland flooding that caused this tropical storm to be one of the most damaging since Hurricane Katrina in 2005. In this paper, we analyze observed precipitation in the Houston area with a nonstationary generalized extreme value (GEV) statistical model (Coles, 2001). Saturation specific humidity increases in a warmer atmosphere according to the Clausius-Clapeyron relationship by about 6–7% per degree local warming in the absence of dynamical changes. As a result of this physical property of air, extreme precipitation is expected to increase by at least this amount as the climate warms due to anthropogenic changes in the composition of the atmosphere (Allen & Ingram, 2002). As the source of the moisture during Hurricane Harvey is clearly from the Gulf of Mexico near the Texas coastline, ocean temperature in the region is a logical choice for a physical covariate in a statistical model of extreme precipitation. However, our purposes here are to find an attributable human influence, if any, to the precipitation during the storm. Sea surface temperatures (SSTs) at any given time, even at the global scale, are determined by a mix of human and natural factors, and it is important to separate these factors for an attribution study (National Academy of Sciences, 2016). The El Niño/Southern Oscillation (ENSO) is the largest natural influence on SST as well as a significant factor in modulating Atlantic hurricane activity (Patricola et al., 2014). While we could remove the effect of ENSO on SST to construct a mostly anthropogenic covariate (Compo & Sardeshmukh, 2010), we instead isolate the human and natural effects on extreme precipitation using two time-dependent covariates: total atmospheric CO2 concentration and Niño3.4, a commonly used ENSO index. There are important caveats to this choice. First, other natural factors apart from ENSO are not accounted for and are “hidden” covarying effects. Second, saturation specific humidity scales with temperature rather than atmospheric composition. Also, while CO2 radiative forcings scale with its natural logarithm (Ramaswamy et al., 2001) and determine equilibrium surface temperatures, the relationship to transient surface temperatures further depends on the efficacy of ocean heat uptake (Winton et al., 2010). Despite these caveats, atmospheric CO2 concentration and Niño3.4 are well measured and provide a reasonable, if not complete way to separate the human and natural influences on extreme precipitation.

2 Data

The data used for our analysis are daily weather station measurements of total precipitation (in millimeters) obtained from the Global Historical Climatology Network (GHCN) over a latitude/longitude box centered on Houston, Texas (covering 26.5°N to 33°N and 91°W to 99°W) from 1 January 1950 to 10 September 2017. Data files and a variety of instructional documentation are available at ftp://ftp.ncdc.noaa.gov/pub/data/ghcn/daily/; the data files used were downloaded at approximately 13:00 PDT on 21 September 2017. Details on data quality control and a plot of all available GHCN stations in the latitude/longitude box are provided in the supporting information.

2.1 Estimation of the Hurricane Harvey Rainfall Totals

The bulk of the precipitation over the Houston, Texas, region was received from 25 to 31 August 2017. Although the GHCN data are updated regularly, not all of the stations in this region contain values for all 7 days. Thus, to ensure that our estimate of the weekly total is appropriate, we only retain stations that have at least five nonmissing daily values during this 7 day period. The remaining individual station measurements are plotted in Figure 1 (left), along with a geostatistical filled-in prediction map (using a stationary Gaussian process model and kriging) in Figure 1 (middle). For comparison, we also show the weekly total downloaded from the NOAA's Advanced Hydrologic Prediction Service (AHPS) in Figure 1 (right) (https://water.weather.gov/precip/index.php), which are quality-controlled, multiple source (radar and rain gauge) precipitation estimates. The general pattern and amount of total precipitation during this week is consistent between the gridded GHCN station and AHPS estimates.

grl56744-fig-0001
Precipitation totals (mm) for the Houston, Texas, region from 25 to 31 August 2017: (left) GHCN stations with at least five nonmissing daily measurements during this time window; (middle) smoothed estimates (using a stationary Gaussian process and kriging) of the GHCN station totals; (right) NOAA's Advanced Hydrologic Prediction Service (AHPS) estimates, based on radar and rain gauge data. The orange and red ellipses correspond to the small and large regions, respectively.

We have divided the GHCN stations into two groups. A larger region defined by the red ellipse (comprising approximately 105,000 km2) contains 247 stations of which only 43 contain the requisite five nonmissing daily values. A smaller region of 83 stations defined by the orange ellipse (comprising approximately 33,000 km2) is centered on the highest values during this week. Only 11 of these stations satisfy our quality control criterion. A map with all of the GHCN stations in Louisiana and Texas is shown in the supporting information. Table 1 summarizes these estimates of Texas precipitation, averaged over all stations or grid cells inside each station group, during Hurricane Harvey. We interpret the range in values for each region as a crude estimate of the observational uncertainty.

Table 1. Precipitation Totals (Pr) in Millimeters for the Houston, Texas, Area Over 25–31 August 2017, Averaged Over Each Region for Each Data Source
Small region Large region
Human- Lower Human- Lower
induced bound induced bound
Pr change in on change Pr change in on change
Data source (mm) magnitude (%) (%) (mm) magnitude (%) (%)
GHCN stations (raw values) 735.0 37.7 18.8 491.6 23.6 6.8
GHCN stations (smoothed) 700.2 37.7 19.3 481.6 23.6 6.9
NOAA AHPS 829.3 37.7 18.3 552.4 23.7 4.8
  • Note. Also shown is the percent change in the magnitude of the observed storm totals from each data source due to human-induced climate change with likely lower bound. See section 4 for more details.

2.2 Historical Data

To place the precipitation totals from Hurricane Harvey in a climatological context, we extract the largest 7 day rainfall total (denoted hereafter as Rx7day) for each GHCN station during hurricane season (July to November) for 1950–2016 from the daily precipitation measurements and calculated a simple arithmetic average as in Table 1. Rx7day values were only recorded if a station had a minimum of 66.7% of daily precipitation measurements in the July–November time interval in a given year, and the recorded Rx7day value refers to a complete 7 day interval with no missing values. While it varies across the time series, on average, there are about 25 stations satisfying this quality control condition in the smaller region and about 80 such stations in the larger region. It is possible (but not likely) that the seasonal maximum values in a particular year occurred from different storms across the stations. The annual time series for each region over 1950–2016 is shown in Figure 2a.

grl56744-fig-0002
(a) Annual values for the largest 7 day total (Rx7day) over 1950–2016, averaged across GHCN stations with nonmissing values within each region. (b) Return period for the previous largest observed Rx7day (solid line; small region = 315.8 mm, large region = 300.3 mm), with 66% (dark band) and 90% (light band) confidence intervals, using observed Niño3.4 and CO2 measurements. (c) Return period for the observed storm total from Hurricane Harvey (using the raw station average from Table 1) with 66% confidence interval, again using observed Niño3.4 and CO2 measurements. (d) Risk ratio comparing the probability of a range of storm totals z for fixed 2017 Niño3.4 but 2017 CO2 versus 1950 CO2 (solid line) with likely lower bound (dashed line).

It should be noted that the even the lowest estimates of the precipitation total during Hurricane Harvey (see Table 1: 700.2 mm for the small region and 481.6 mm for the large region) are significantly larger than the previous record for each group of stations over 1950–2016 (315.8 mm for the small region and 300.3 mm for the large region). The 2017 storm totals are intentionally left off of the observed time series in Figure 2a in order to more appropriately visualize the variability over 1950–2016. We provide some discussion in section 5 on how the magnitude of the precipitation accumulations during Hurricane Harvey impact our analysis.

3 Extreme Value Analysis

An extreme value analysis was conducted for each group of stations based on the Rx7day time series in Figure 2a for 1950–2016. We intentionally exclude the 2017 observed precipitation values from our statistical model in order to perform an “out of sample” analysis of Hurricane Harvey precipitation in the sense of an a priori prediction. While there are several different ways to characterize the extreme values of an atmospheric process (see, e.g., Coles, 2001), we use a block maxima approach and the generalized extreme value (GEV) family of distributions. The block maxima approach specifies a statistical model for urn:x-wiley:grl:media:grl56744:grl56744-math-0001, where the {Yti,i = 1,…,n} are individual measurements (here seven daily precipitation totals) within “block” t (here July to November of year t). Statistical theory says that the cumulative distribution function (CDF) of Zt is a member of the GEV family
urn:x-wiley:grl:media:grl56744:grl56744-math-0002(1)
defined for {z:1 + ξt(zμt)/σt>0}. The GEV family of distributions 1 is characterized by three parameters: the location parameter urn:x-wiley:grl:media:grl56744:grl56744-math-0003 (which describes the center of the distribution), the scale parameter σt>0 (which describes the spread of the distribution), and the shape parameter urn:x-wiley:grl:media:grl56744:grl56744-math-0004. The shape parameter ξt determines the qualitative behavior of the distribution of maximum Rx7day rainfall: if ξt<0, the distribution has a finite upper bound of μtσt/ξt; if ξt>0, the distribution has no upper limit; if ξt=0, the distribution is again unbounded and the CDF 1 is interpreted as the limit urn:x-wiley:grl:media:grl56744:grl56744-math-0005 (Coles, 2001).

As the notation in 1 suggests, we wish to allow the GEV parameters {μt,σt,ξt} to vary over a set of years {t = 1,…,T}, so that we can characterize changes in the distribution of Rx7day over time. As outlined in section 1, two covariates are used to describe the temporal variations in extreme precipitation: seasonally averaged global CO2 and annually averaged Niño3.4 index. While other choices of suitable covariates are possible, these two were chosen as they provide a clear distinction between natural and human influences. Niño3.4 values are based on the ERSSTv5 monthly index from NOAA's National Center for Environmental Prediction (http://www.cpc.ncep.noaa.gov/data/indices/). The CO2 measurements are a combined time series of data used as input for climate models (from the International Institute for Applied Systems Analysis or IIASA; see https://tntcat.iiasa.ac.at/RcpDb) and the record from the Mauna Loa Observatory (MLO). The IIASA values are based on actual observations for 1950–2005; hence, we extend these from 2006 to 2017 using the MLO values. We must use this combined time series to take advantage of the 1950–2016 GHCN data, as the MLO CO2 record only goes back to 1958. The Niño3.4 and CO2 covariates are plotted in the supporting information.

As with mean regression (also known as ordinary least squares), we can specify linear relationships between these covariates and the GEV parameters to estimate the coefficients for each covariate. Using the CO2 and Niño3.4 covariates to characterize changes over time in Rx7Day, we consider four different trend models for the GEV parameters:
  1. Model M0, where all of the GEV parameters are constant over time:
    urn:x-wiley:grl:media:grl56744:grl56744-math-0006
  2. Model M1, where both the location and scale parameters depend linearly on only urn:x-wiley:grl:media:grl56744:grl56744-math-0007):
    urn:x-wiley:grl:media:grl56744:grl56744-math-0008
  3. Model M2, where the location parameter depends linearly on both urn:x-wiley:grl:media:grl56744:grl56744-math-0009) and Niño3.4 and the log of the scale parameter depends linearly on urn:x-wiley:grl:media:grl56744:grl56744-math-0010) only:
    urn:x-wiley:grl:media:grl56744:grl56744-math-0011
  4. Model M3, where the location and log of the scale parameters depend linearly on both urn:x-wiley:grl:media:grl56744:grl56744-math-0012) and Niño3.4:
    urn:x-wiley:grl:media:grl56744:grl56744-math-0013

In the above, urn:x-wiley:grl:media:grl56744:grl56744-math-0014 in year t and x2t= the Niño3.4 index value for year t. We only consider models in which the shape is constant over time because we believe the data do not provide enough information to estimate a time-varying shape parameter. Our reasoning for this choice follows from Cooley et al. (2007), who found that a constant shape parameter yielded better results compared to a statistical model that allowed the shape parameter to vary across the domain of interest (in their case, over a spatial domain). The Akiake Information Criterion (AIC) clearly selects model M2 as best for both regions (see the supporting information for more details), indicating that model M2 preserves the most information of the four models tested.

Maximum likelihood estimation is used to obtain best estimates of all statistical parameters in model M2 for both groups of stations via the climextRemes package for R (Paciorek, 2016), and the bootstrap is used to quantify uncertainty in these estimates (see the supporting information for more details). The best estimates and the bootstrap are also used to estimate return values (i.e., quantiles of the distribution of Rx7day), return probabilities (i.e., the probability of a particular magnitude storm occurring in each year), and return periods (i.e., the inverse return probability); again, see the supporting information. Note that this nonstationary model allows us to characterize changes over time by suitable variation of either or both of the two physical covariates, so that we can isolate the effects of both natural and human sources of variation in extreme precipitation.

4 Results

Best estimates and confidence intervals for each of the GEV coefficients for both regions are given in the supporting information. The 90% confidence intervals of the CO2 and Niño3.4 coefficients in the location parameters (β1 and β2) do not include zero, indicating that it is very likely that both human and natural processes cause observed changes over time in the center of the GEV distribution. In this statement as well as elsewhere in the paper, we use the terms likely and very likely as a “likelihood” statement as defined by the Intergovernmental Panel on Climate Change (IPCC, Mastrandrea et al., 2010). Although the best estimate of the CO2 coefficient for the log scale parameter (ϕ1) is positive, indicating that the variability of the GEV distribution increases with CO2, the 66% confidence interval includes zero precluding an IPCC-style likelihood statement about the anthropogenic influence on the variability of hurricane season maximum precipitation in Texas. Finally, the best estimate of the shape parameter is positive ( urn:x-wiley:grl:media:grl56744:grl56744-math-0015), meaning that the fitted distribution of Rx7day is heavy tailed and unbounded (this is consistent with other extreme value analyses involving precipitation), but confidence intervals also include negative values, indicating the possibility of a bounded distribution. While the actual distribution of extreme precipitation is of course bounded, fitted unbounded distributions to extreme precipitation are not uncommon (Cooley et al., 2007).

While estimates of the GEV coefficients can be insightful, for attribution purposes we are more interested in exploring how return values, return periods, and return probabilities have changed as a result of the anthropogenic increases in atmospheric CO2 concentrations while accounting for the natural influence of ENSO. Conditional on the fitted statistical models, we first estimate the return periods in each region for the largest previously observed value of Rx7day, namely, 315.8 mm for the small region of Figure 1 and 300.3 mm for the large region (these values both occurred in 1998; see Figure 2a). The best estimate of the return periods for these 7 day precipitation totals are shown from 1950 to 2017 in Figure 2b with a solid line. The 66% and 90% confidence intervals are shown with the dark and light bands, respectively. Note that the return period and confidence intervals are calculated for each year using observed values of both Niño3.4 and CO2. The uncertainty is quite large at the 90% confidence level, but there is a steady decrease in the return periods for each region. This indicates that the largest previously observed Rx7day total has become much more commonplace: from a several hundred year storm in 1950 to a 25–50 year storm in 2017. Our covariate-based analysis indicates that this change is due to the anthropogenic increase in atmospheric CO2 concentrations and not natural ENSO variability. Figure 2c shows the change in return periods estimated using the station averages of Rx7day from Table 1 during Hurricane Harvey. Estimated return periods and their statistical uncertainties are significantly larger than for the previously largest observed precipitation total in Figure 2a. A visual inspection of the return period plots in both Figures 2b and 2c reveals that large magnitude storms are becoming more common.

The covariate-based statistical models permit isolation of the effect of anthropogenic warming on the probability of large storms under fixed ENSO conditions. This is accomplished by first estimating the probability of the Rx7day total in the current year, Z, exceeding some threshold z conditional on a fixed Niño3.4 index, say, that observed in 2017, and on CO2 concentrations in that same year, or
urn:x-wiley:grl:media:grl56744:grl56744-math-0016
(the vertical bar “|” means “conditional on”). Next, we calculate a similar probability, but in a counterfactual world with a similar ocean state (as described by the Niño3.4 index) but earlier (say, 1950) CO2 concentrations,
urn:x-wiley:grl:media:grl56744:grl56744-math-0017
Comparison of the likelihood of events of fixed magnitude is commonly termed “probabilistic event attribution” (Pall et al., 2014) and explores the ratio of these probabilities referred to as the “risk ratio” for z,
urn:x-wiley:grl:media:grl56744:grl56744-math-0018(2)

(see, e.g., Jeon et al., 2016; Risser et al., 2017; Paciorek et al., 2017). Here we mean “risk” in the epidemiological or relative sense. Figure 2d shows the best estimate of this risk ratio in each region for precipitation totals ranging from 300 mm to 1,000 mm (solid line) as well as a likely (66%) lower confidence bound. The best estimate of the risk ratio in both regions is larger than 4 over this entire range of precipitation totals. The likely lower bound on the risk ratio is decidedly larger than 1 for both regions and all values of z and in fact is larger than 3 for the small region. For the average station data totals (see Table 1: 735.0 mm for the small region and 491.6 mm for the large region), the best estimate of the risk ratio is 9.6 (with a likely lower bound of 3.5) in the small region and 5.0 (with a likely lower bound of 1.4) in the large region. These risk ratio lower bound estimates are notably insensitive to choice of the value of z and hence would not change much across the observational uncertainty of the Hurricane Harvey precipitation totals (Table 1) or even much larger storm total uncertainty estimates.

It is important to note that our analysis is based only on observational data. Therefore, any attribution statement made here must be interpreted in the Granger causality sense (Granger, 1969) as a measure of predictability based on the statistical model. The more traditional framework for event attribution studies (National Academy of Sciences, 2016) uses Pearl's definition of causality (Hannart et al., 2016; Pearl, 1988), which is based on intervention (e.g., using dynamical climate models to construct a counterfactual climate scenario) and can be used to prove causal connections. Observational analyses with Granger causality cannot prove causal connections but are still powerful in that they can disprove causal connections as well as establish a lower bound for an attribution statement like the risk ratio (Ebert-Uphoff & Deng, 2012). For Hurricane Harvey, our predictive model suggests that there is a likely human-induced increase in the chances of reaching the observed rainfall totals since the risk ratio is well above one for both regions considered and over a wide range of plausible precipitation estimates. We also disprove that this influence is very likely, as the 90% lower bound on the risk ratio estimate is less than unity (not shown). The Granger interpretation of these statements establishes an upper bound on the uncertainty language (Mastrandrea et al., 2010), based on the length of observational record with a fixed number of hurricanes. This conclusion motivates future dynamical climate modeling studies of this event that could arrive at stronger conclusions by enabling the simulation of a large number of factual and counterfactual storms.

In addition to quantifying changes in the probability of the observed Hurricane Harvey precipitation, it is also useful to estimate the amount of excess precipitation attributable to global warming. We do this here by estimating the change since 1950 in return value for the (fixed) contemporary probability estimate of the observed precipitation total. In other words, we estimate the return period, w, for an estimated precipitation total z in 2017 using current values of the Niño3.4 index and CO2 levels. We then compare the return value z at this same return period w estimated with the current Niño3.4 index but 1950 CO2 levels to the actual observation as a percent change. Best estimates of the attributable percent difference are provided in Table 1 for the range of estimated Hurricane Harvey precipitation, along with the likely (66%) lower confidence bound. In the small region, the best estimate of the change is well over 30% for all data sources, with a likely increase around 18–19%. In the large region the best estimate of this attributable difference is lower, around 23%, with a likely increase of about 5–7%. These more mechanistic attribution statements (Easterling et al., 2016) are to be interpreted as lower bounds on the change in magnitude and upper bounds on the uncertainty language, again as dictated by the Granger causality framework. Previous analysis (Pall et al., 2017) suggests that the local warming of the Gulf of Mexico attributable to anthropogenic climate change is about 1°C since the preindustrial era. As most of that warming occurred after 1950, a plausible lower bound on the excess total precipitation during Hurricane Harvey is 6–7% as dictated by the Clausius-Clapeyron (C-C) scaling of saturation specific humidity (Allen & Ingram, 2002). While our likely estimate for the lower bound in the large region is consistent with C-C scaling, it is substantially larger for the wetter small region. A possible interpretation for this result is that within the most heavily precipitating parts of Hurricane Harvey, precipitation efficiency is increased due to factors other than C-C scaling (Pall et al., 2017) but at larger scales total precipitation is indeed limited by the amount of available humidity. The consistency of our lower bound on the magnitude of precipitation changes in the large region with C-C scaling enhances confidence in the Granger interpretation of our statistical model's results. Confirmation or dispute of this interpretation again requires dynamical climate modeling studies of this event.

5 Conclusions

Significant changes in both the likelihood and magnitude of observed precipitation totals in the Houston, Texas, region from Hurricane Harvey are likely attributable to anthropogenic climate change. These conclusions are consistent with a related analysis of the 2016 flooding in Louisiana (van der Wiel et al., 2017), although our attribution statement is more conservative. We interpret our attribution statement in the Granger causality sense, as it is a result of a nonstationary extreme value statistical analysis of the observations alone. As such, this statement should be considered as a lower bound both on the changes in frequency, expressed as the risk ratio, and on the magnitude. A stronger attribution statement that could be interpreted in a Pearl causality sense must await dynamical model analyses with explicit intervention to isolate the anthropogenic influences.

We also find that changes in the likely lower bound on the risk ratio are relatively insensitive to observational error in precipitation magnitude from Hurricane Harvey. Furthermore, the attributable changes found in this analysis suggest a sizable human influence on this storm's precipitation. In the wettest part of the storm, it is likely that the attributable precipitation increase significantly exceeds that suggested from a simple Clausius-Clapeyron scaling dictated by the attributable increases in Gulf of Mexico surface air temperatures. Confidence in such a super Clausius-Clapeyron effect relies on postulating a plausible physical mechanism to increase the storms efficiency in precipitating available moisture (which is likely limited by the Clausius-Clapeyron relationship). Hopefully, dynamical modeling studies will either confirm or dispute this behavior.

Finally, we reiterate that Hurricane Harvey was an unusual storm largely due to the lengthy period it spent stalled over Texas. Precipitation rates were not particularly unusual for a hurricane of this magnitude (B. Russell, private communication, 2017), and the human-induced changes to precipitation metrics that consider less than the 7 day storm total are smaller than the results presented here. Also, as mentioned in section 2, the precipitation totals during Hurricane Harvey are significant outliers relative to the previous historical record. As such, this calls into question the appropriateness of any standard extreme value analysis since the 2017 storm total could be the result of a physical processes that did not occur during 1950–2016. This issue has been encountered in other contexts involving observational data, for example, wave buoy measurements (Timmermans et al., 2017). In our case, the out of sample (i.e., a priori) estimates of several thousand year return periods for the observed 2017 precipitation (Figure 2c) are probably too large, given that what we are only considering measurements dating back to 1950. Regardless, we note that the changes in extreme statistics of hurricane season precipitation along the Texas coast are remarkably robust. This is evident in the lower bound of the risk ratios in Figure 2d, which are stable over a large range of storm total precipitation from the previous record of around 300 mm to well above the 2017 observations.

Acknowledgments

The authors would like to thank William D. Collins and Benjamin W. Timmermans for helpful discussions, as well as two anonymous reviewers for helpful comments and suggestions. The data supporting this article are based on publicly available measurements from the National Centers for Environmental Information (at ftp://ftp.ncdc.noaa.gov/pub/data/ghcn/daily/). We furthermore note that the key points report what is learned from this study. This research was supported by the Director, Office of Science, Office of Biological and Environmental Research of the U.S. Department of Energy under contract DE-AC02-05CH11231. This document was prepared as an account of work sponsored by the United States Government. While this document is believed to contain correct information, neither the United States Government nor any agency thereof, nor the Regents of the University of California, nor any of their employees, makes any warranty, express or implied, or assumes any legal responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by its trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof, or the Regents of the University of California. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof or the Regents of the University of California.